Ah, understood. Ok, first, you are correct that charging from the high side is going to be difficult due to the pressure difference. That gives us one other option.
But before that, here's what I recommend for changing the valve itself:
Step 1: Close receiver outlet valve.
Step 2: Let system run until it shuts itself off at low suction cutoff point.
Step 2A: Turn off power, and close discharge service valve.
Step 3: Recover freon from just the low side
Step 4: Remove all fittings from suction service valve
Step 5: Unbolt suction service valve
Step 6: Clean surface thoroughly (regular scouring pad should work)
Step 7: Put on new valve gasket and valve, and bolt it down
Step 8: Reattach all the lines
Step 9: Evacuate low side of system
Step 9A: Open discharge service valve (back seat)
Step 10: Open your receiver outlet valve (make sure it's fully evacuated)
Step 10A: Turn power back on
Step 11: Let system run
Step 12 (if needed): Slowly add liquid freon to low side. Very slowly, around 1 ounce per minute. Only do this if the system is low, if it's still good from your last recharge, you shouldn't have to do this.
Questions from me: Does your system have a high pressure cutoff switch? If so, where is the sensor line located?