I have got a 40 year old brno 308. I bought it from an old timer for a few hundred dollars, it looked in pretty good condition. I probably doubled its lifetime shots through it in my first 2 years of hunting and target shooting. It was perfectly accurate for bushveld hunting (200 yards). I developed a few slower, low recoil loads for it so my younger son could come hunting with me. That's when I noticed a serious first shot accuracy problem. (cold barrel, fouled bore). Would go to the range and subsequent shots would be 1 or 2 inches accurate but first shot would have up to 6 inch drop at 100m, subsequent shots on a warm bore were accurate. With subsonic rounds the first shot drop was as much as a foot over 60 yards!
Of course with hunting, cold bore fouled barrel are the 90 percent of the important shots taken.
I did a rigorous clean with hoppes no 9 bench, it took me about 3 weeks, scrubbing with nylon brush every day and leaving overnight, the blue liquid would be on the swab every morning.
When the nylon brush stopped dislodging copper I took out the phosphorbronze brush and the copper started appearing again, occasionally interspersed with layers of carbon, then back to copper. This went on for about 20 cleaning sessions. Never got all the copper out but the swabs were clean.
Wore out 2 phosphorbronze brushes.
Went back to the range and problem solved.
Now I never let it build up again but I never get down to bare steel again either.
I do a wire brush scrubbing and 3 times overnight soak after every hunting trip and am careful to test if the problem is back.
Switched to Cfe223 powder for some of my lighter faster hunting loads and it doesn't eliminate the copper as claimed, but it does reduce it, or at least convert it to some Grey brown substance that takes much brushing to remove.
That first shot must go where you send it otherwise you lose your confidence, which causes you to compensate and hold over too high on the follow up shot which then goes doubly high.
Interested to hear if someone has experienced this on a rifle made this century?